Introduction
Silver nanowires are extremely thin silver wires that have diameters measuring only tens to hundreds of nanometers wide but can be several micrometers in length. They have unique properties that make them promising candidates for a wide range of applications in electronics, optics, and health.
What are Silver Nanowires?
Silver nanowires are nanostructures made of silver that have at least one dimension in the nanoscale range (1-100 nanometers). Their small size gives them novel optical, electrical and thermal properties compared to bulk silver materials. Silver Nanowires are flexible, highly conductive and transparent. Because of these special characteristics, scientists are researching ways to utilize silver nanowires in new technologies.
Making Silver Nanowires
There are a few main methods used for producing silver nanowires in the lab:
Polyol Process - This is one of the most common synthesis techniques. It involves using a polyol like ethylene glycol both as a reducing agent and as a solvent. Silver nitrate is added along with a structure-directing agent like hexadecylamine or polyethylene glycol. As the solution is heated, it causes the silver ions to reduce and form long nanowire structures.
PVP-Assisted Synthesis -This method uses polyvinylpyrrolidone (PVP) as a capping agent to help control the growth of silver nanowires. Solutions of PVP, silver nitrate and ethylene glycol are heated to allow nanowires to form through a redox reaction.
Template-Assisting Methods -Templates like porous aluminum oxide membranes can be used to guide the formation of nanowires with specific shapes and diameters. Electrochemical deposition is used to grow silver within the nanopores of the template.
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