All consumers were also at the threshold carcinogenic risk of As (between 10-4 and 10-6). Given the considerable health risks due to consumption (refined, rock, and sea salt), approaching effective monitoring plans to control the PTEs concentrations in salt distributed in Tehran are recommended.The frequent and extensive use of insecticides has caused serious aquatic pollution, thus posing a great threat to ecosystems and public health. In this study, three classes of insecticides including 20 organochlorine pesticides (OCPs), 6 organophosphorus pesticides (OPs), and 8 pyrethroids were analyzed in 24 sediments from the Liaohe River basin. The results showed that all sediment samples were contaminated with insecticides, with the total concentrations ranging from 7.3 ng/g dry weight (dw) to 242.8 ng/g dw. Among them, pyrethroids (2.2-102.5 ng/g dw) contributed 55% of the total insecticide concentration, followed by OCPs (1.3-94.8 ng/g dw) and OPs (2.6-45.5 ng/g dw), representing 24% and 21% of the total concentrations, respectively. For OCPs, hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) showed the highest concentrations of 0.37-37.5 ng/g dw and 0.05-23.2 ng/g dw, respectively. Historical inputs of lindane and technical DDT were the major sources of HCHs and DDTs, respectively, as indicated by isomer or metabolite ratios. Additionally, dichlorvos (0.26-17.1 ng/g dw) was the main OP, while cypermethrin dominated the pyrethroids with the concentrations of 1.6-32.6 ng/g dw. The spatial distribution revealed that significantly higher residues of insecticides were observed in sediments from the Daliao River system than those from the Liao River. This implied that these insecticides were most likely from the discharge of highly polluted sewage and industrial wastewater from adjacent industrial and populous cities as well as urban applications (e.g., landscape maintenance and household pest control). An ecological risk assessment based on risk quotients suggested that the three classes of insecticides analyzed here pose a low risk to aquatic organisms in the study area.Residential buildings consume a major portion of energy resources and hence are seriously involved in environmental pollution. In Iran, fossil fuel consumption is growing, such that it increased by more than 400% from 1990 to 2018. One of the fundamental solutions for reducing fossil fuel consumption and creating a healthy environment inside and outside buildings is implementing and developing green buildings. This study seeks to examine the barriers to and opportunities for developing green buildings and proposes a localized green standard appropriate for the conditions of Iran. To this end, the required parameters were identified using the opinions of experts and the Delphi method. The opinions of 81 building experts, including the employers, consultants, and contractors, were obtained using a three-part questionnaire. Based on the results from the machine learning method, the score of the localized green building in five dimensions, namely, site, water, energy, materials, and quality of the indoor environment was calculated to be 77.2, while the energy dimension was determined to be the most important green standard dimension with a significance coefficient of 0.548. In the ranking analysis of all parameters using the Friedman test, the parameters of energy consumption management, renewable energy usage, and thermal zoning received the highest scores among other factors. Furthermore, a lack of awareness on green buildings (77%) and a high potential for renewable energy production (81%) were respectively identified as the biggest barrier to and opportunity for the implementation of green buildings in Iran.For many decades, titanium dioxide (TiO2) semiconductor has been extensively applied in several environmental applications due to its higher photocatalytic performances toward different organic pollutants, pharmaceutical compounds, and bacteria. https://www.selleckchem.com/products/xst-14.html However, its shortfall response to visible light, and the expeditious recombination rate of the photogenerated electron-hole pairs, hampers its utilization. Doping TiO2 semiconductor with silver nanoparticles is a sound strategy to (1) extend its photocatalytic activity to visible light, (2) prevent the electron/holes pairs recombination due to the formation of the Schottky barrier at the interfaces with TiO2 that act as an electron-trapping center, and (3) enhance its bactericide performances. This review focuses on the recent progress on silver-doped titanium dioxide (Ag/TiO2)-based photocatalysts. It addresses a wide range of Ag/TiO2 synthesis techniques, their physicochemical properties and discusses thoroughly the important role of silver (Ag) nanoparticles in enhancing the removal capacity and antibacterial performances of the Ag/TiO2 photocatalysts.Disposable face mask has become a mandatory personal protective equipment in order to prevent contracting COVID-19. With the significant surge in its usage, its adverse environmental impact is becoming a source of concern. Disposable face masks are made from thermoplastic polymers, and therefore they can be safely converted into valuable bioproducts. This paper discussed the possibility of converting waste/contaminated face masks into valuable bioproducts, which will essentially eliminate secondary transmission of the coronavirus and the concerns of environmental pollution.The Phl p 5 allergen of the plant species Phleum pratense is considered one of the most crucial grass pollen allergenic molecules inducing respiratory allergies. In this study, we evaluated seasonal variation in the concentration of both grass pollen and Phl p 5 allergens as well as the ratio allergen/pollen (pollen potency) in the air of Bratislava during two consecutive years, 2019-2020. These 2 years differed in terms of air pollution, as COVID-19 lockdown in spring 2020 considerably improved air quality in the study area. Air samples were collected using a Hirst-type sampler for pollen detection and the cyclone sampler for aeroallergen detection. In 2020, we observed 80.3% higher seasonal pollen integral, probably associated with the longer pollen season duration, however, 43.6% lower mean daily pollen potency than in 2019. The mean daily pollen value was 37.5% higher in 2020 than in the previous year, while the mean daily allergen value was 14.9% lower in 2020. To evaluate the relationship between the amount of pollen or allergen in the air and selected meteorological factors and air pollution parameters, we used multiple regression analysis.
All consumers were also at the threshold carcinogenic risk of As (between 10-4 and 10-6). Given the considerable health risks due to consumption (refined, rock, and sea salt), approaching effective monitoring plans to control the PTEs concentrations in salt distributed in Tehran are recommended.The frequent and extensive use of insecticides has caused serious aquatic pollution, thus posing a great threat to ecosystems and public health. In this study, three classes of insecticides including 20 organochlorine pesticides (OCPs), 6 organophosphorus pesticides (OPs), and 8 pyrethroids were analyzed in 24 sediments from the Liaohe River basin. The results showed that all sediment samples were contaminated with insecticides, with the total concentrations ranging from 7.3 ng/g dry weight (dw) to 242.8 ng/g dw. Among them, pyrethroids (2.2-102.5 ng/g dw) contributed 55% of the total insecticide concentration, followed by OCPs (1.3-94.8 ng/g dw) and OPs (2.6-45.5 ng/g dw), representing 24% and 21% of the total concentrations, respectively. For OCPs, hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) showed the highest concentrations of 0.37-37.5 ng/g dw and 0.05-23.2 ng/g dw, respectively. Historical inputs of lindane and technical DDT were the major sources of HCHs and DDTs, respectively, as indicated by isomer or metabolite ratios. Additionally, dichlorvos (0.26-17.1 ng/g dw) was the main OP, while cypermethrin dominated the pyrethroids with the concentrations of 1.6-32.6 ng/g dw. The spatial distribution revealed that significantly higher residues of insecticides were observed in sediments from the Daliao River system than those from the Liao River. This implied that these insecticides were most likely from the discharge of highly polluted sewage and industrial wastewater from adjacent industrial and populous cities as well as urban applications (e.g., landscape maintenance and household pest control). An ecological risk assessment based on risk quotients suggested that the three classes of insecticides analyzed here pose a low risk to aquatic organisms in the study area.Residential buildings consume a major portion of energy resources and hence are seriously involved in environmental pollution. In Iran, fossil fuel consumption is growing, such that it increased by more than 400% from 1990 to 2018. One of the fundamental solutions for reducing fossil fuel consumption and creating a healthy environment inside and outside buildings is implementing and developing green buildings. This study seeks to examine the barriers to and opportunities for developing green buildings and proposes a localized green standard appropriate for the conditions of Iran. To this end, the required parameters were identified using the opinions of experts and the Delphi method. The opinions of 81 building experts, including the employers, consultants, and contractors, were obtained using a three-part questionnaire. Based on the results from the machine learning method, the score of the localized green building in five dimensions, namely, site, water, energy, materials, and quality of the indoor environment was calculated to be 77.2, while the energy dimension was determined to be the most important green standard dimension with a significance coefficient of 0.548. In the ranking analysis of all parameters using the Friedman test, the parameters of energy consumption management, renewable energy usage, and thermal zoning received the highest scores among other factors. Furthermore, a lack of awareness on green buildings (77%) and a high potential for renewable energy production (81%) were respectively identified as the biggest barrier to and opportunity for the implementation of green buildings in Iran.For many decades, titanium dioxide (TiO2) semiconductor has been extensively applied in several environmental applications due to its higher photocatalytic performances toward different organic pollutants, pharmaceutical compounds, and bacteria. https://www.selleckchem.com/products/xst-14.html However, its shortfall response to visible light, and the expeditious recombination rate of the photogenerated electron-hole pairs, hampers its utilization. Doping TiO2 semiconductor with silver nanoparticles is a sound strategy to (1) extend its photocatalytic activity to visible light, (2) prevent the electron/holes pairs recombination due to the formation of the Schottky barrier at the interfaces with TiO2 that act as an electron-trapping center, and (3) enhance its bactericide performances. This review focuses on the recent progress on silver-doped titanium dioxide (Ag/TiO2)-based photocatalysts. It addresses a wide range of Ag/TiO2 synthesis techniques, their physicochemical properties and discusses thoroughly the important role of silver (Ag) nanoparticles in enhancing the removal capacity and antibacterial performances of the Ag/TiO2 photocatalysts.Disposable face mask has become a mandatory personal protective equipment in order to prevent contracting COVID-19. With the significant surge in its usage, its adverse environmental impact is becoming a source of concern. Disposable face masks are made from thermoplastic polymers, and therefore they can be safely converted into valuable bioproducts. This paper discussed the possibility of converting waste/contaminated face masks into valuable bioproducts, which will essentially eliminate secondary transmission of the coronavirus and the concerns of environmental pollution.The Phl p 5 allergen of the plant species Phleum pratense is considered one of the most crucial grass pollen allergenic molecules inducing respiratory allergies. In this study, we evaluated seasonal variation in the concentration of both grass pollen and Phl p 5 allergens as well as the ratio allergen/pollen (pollen potency) in the air of Bratislava during two consecutive years, 2019-2020. These 2 years differed in terms of air pollution, as COVID-19 lockdown in spring 2020 considerably improved air quality in the study area. Air samples were collected using a Hirst-type sampler for pollen detection and the cyclone sampler for aeroallergen detection. In 2020, we observed 80.3% higher seasonal pollen integral, probably associated with the longer pollen season duration, however, 43.6% lower mean daily pollen potency than in 2019. The mean daily pollen value was 37.5% higher in 2020 than in the previous year, while the mean daily allergen value was 14.9% lower in 2020. To evaluate the relationship between the amount of pollen or allergen in the air and selected meteorological factors and air pollution parameters, we used multiple regression analysis.
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