The oxyanions also reduce the crystallinity and particle sizes of the transformation products, ascribed to adsorption of the oxyanions on the products, preventing their further particle growth. This study enriches our understanding of the solution chemistry control on redox-driven transformation of Mn oxides.A comparative investigation of the post-electroplating treatment influence on the gas detecting performances of single ZnO nanorod/nanowire (NR/NW), as grown by electrochemical deposition (ECD) and integrated into nanosensor devices, is presented. In this work, hydrothermal treatment (HT) in a H2O steam and conventional thermal annealing (CTA) in a furnace at 150 °C in ambient were used as post-growth treatments to improve the material properties. Herein, the morphological, optical, chemical, structural, vibrational, and gas sensing performances of the as-electrodeposited and treated specimens are investigated and presented in detail. By varying the growth temperature and type of post-growth treatment, the morphology is maintained, whereas the optical and structural properties show increased sample crystallization. It is shown that HT in H2O vapors affects the optical and vibrational properties of the material. After investigation of nanodevices based on single ZnO NR/NWs, it was observed that higher temperature during the synthesis results in a higher gas response to H2 gas within the investigated operating temperature range from 25 to 150 °C. CTA and HT or autoclave treatment showed the capability of a further increase in gas response of the prepared sensors by a factor of ∼8. Density functional theory calculations reveal structural and electronic band changes in ZnO surfaces as a result of strong interaction with H2 gas molecules. Our results demonstrate that high-performance devices can be obtained with high-crystallinity NWs/NRs after HT. The obtained devices could be the key element for flexible nanoelectronics and wearable electronics and have attracted great interest due to their unique specifications.The action mechanism of anticancer gold(III) complexes is a multi-step process and depends on their redox stability. https://www.selleckchem.com/products/Semagacestat(LY450139).html First, the gold(III) complex undergoes a ligand exchange reaction in the presence of cellular thiols, such as those available in the active site of the enzyme TrxR, and then, the AuIII → AuI reduction occurs. Most experimental and theoretical studies describe these processes under chemical conditions without considering the enzyme structure effect. In the present study, molecular models are proposed for the [AuIII(C^N^C)(SHCys-R)]+ adduct, with the [AuIII(C^N^C)]+ moiety bonded to the Cys498 residue in the C-terminal arm of the TrxR. This one represents the product of the first ligand exchange reaction. Overall, our results suggest that the exchange of the auxiliary ligand (for instance, Cl- to S-R) plays a primary role in increasing the reduction potential, with the enzyme structure having a small effect. The parent compound [AuIII(C^N^C)Cl] has E° = -1.20 V, which enlarges to -0.72 V for [AuIII(C^N^C)CH3SH]+ and to -0.65 V for the largest model studied, Au-trx. In addition to the effect of the enzyme structure on the redox stability, we also analyze the Au transfer to the enzyme using a small peptide model (a tetramer). This reaction is dependent on the Cys497 protonation state. Thermodynamics and kinetic analysis suggests that the C^N^C ligand substitution by Cys497 is an exergonic process, with an energy barrier estimated at 20.2 kcal mol-1. The complete transfer of the Au ion to the enzyme's active site would lead to a total loss of enzyme activity, generating oxidative damage and, consequently, cancer cell death.The partitioning of solutes into the polyamide active layers of reverse osmosis (RO) membranes is a key membrane property determining solute permeation. Quantification of partition coefficients and their dependence on feedwater pH would contribute to the development of predictive transport models of contaminant transport through RO membranes; however, neither solute partitioning nor the effect of feed solution pH on partitioning has been thoroughly characterized in the literature. Accordingly, we characterized the partitioning of all chloride salts of alkali metals (CsCl, RbCl, KCl, NaCl, and LiCl) from the aqueous phase into the polyamide active layers of five polyamide RO membranes, including one prepared in-house and four commercial membranes. We evaluated the effect of pH on the partitioning of alkali metal salts and whether the effect of pH on salt partitioning and rejection is consistent with Donnan theory predictions. Results showed that for all membranes, the partition coefficients of all salts were less than one and did not differ substantially among RO membranes. Results also indicated that for all membranes tested, Donnan theory provided an appropriate theoretical framework to estimate the effect of pH on salt partitioning (evaluated for all chloride salts of alkali metals) and salt rejection (evaluated for NaCl). Thus, we conclude that changes in salt rejection resulting from feed solution pH are primarily driven by changes in salt partitioning with comparatively small changes in salt diffusion coefficients.The development of smart and eco-friendly fertilizers is pivotal to guarantee food security sustainably. Phosphate rock and struvite are promising alternatives for P fertilization; nevertheless, the solubility of these sources is a challenge for consistent use efficiency. Here, we propose using a polysulfide obtained via inverse vulcanization as a novel controlled-release fertilizer matrix in a system containing either Bayóvar rock (Bay) or struvite (Str). The polysulfide provides S for plants after being biologically oxidized to sulfate in soil, generating local acidity for P solubilization. After 15 days of soil incubation, the composites with 75 wt % Str and 75 wt % Bay achieved, respectively, 3 and 2 times the S oxidation from the elemental sulfur reference. Results indicated that P content stimulates the soil microorganisms' activity for S oxidation. The matrix had a physical role in improving Bay dissolution and regulating the rapid release from Str. Moreover, the available P in soil was 25-30 mg/dm3 for Bay composites, while for pure Bay, it was 9 mg/dm3.