We study periodic arrays of impurities that create localized regions of expansion, embedded in two-dimensional crystalline membranes. These arrays provide a simple elastic model of shape memory. As the size of each dilational impurity increases (or the relative cost of bending to stretching decreases), it becomes energetically favorable for each of the M impurities to buckle up or down into the third dimension, thus allowing for of order 2^M metastable surface configurations corresponding to different impurity "spin" configurations. With both discrete simulations and the nonlinear continuum theory of elastic plates, we explore the buckling of both isolated dilations and dilation arrays at zero temperature, guided by analogies with Ising antiferromagnets. We conjecture ground states for systems with triangular and square impurity superlattices, and comment briefly on the possible behaviors at finite temperatures.The phenomenology of Landau theory with spatial coupling through diffusion has been widely used in the study of phase transitions and patterning. Here we follow this theory and apply it to study theoretically and numerically continuous and discontinuous transitions to periodic spatial cellular patterns driven by lateral inhibition coupling. As opposed to diffusion, lateral inhibition coupling drives differences between adjacent cells. We analyze the appearance of errors in these patterns (disordered metastable states) and propose mechanisms to prevent them. These mechanisms are based on a temporal-dependent lateral inhibition coupling strength, which can be mediated, among others, by gradients of diffusing molecules. The simplicity and generality of the framework used herein is expected to facilitate future analyses of additional phenomena taking place through lateral inhibition interactions in more complex scenarios.We study dynamical signatures of quantum chaos in one of the most relevant models in many-body quantum mechanics, the Bose-Hubbard model, whose high degree of symmetries yields a large number of invariant subspaces and degenerate energy levels. The standard procedure to reveal signatures of quantum chaos requires classifying the energy levels according to their symmetries, which may be experimentally and theoretically challenging. We show that this classification is not necessary to observe manifestations of spectral correlations in the temporal evolution of the survival probability, which makes this quantity a powerful tool in the identification of chaotic many-body quantum systems.The dynamics of magnetization relaxation in ferrofluids are studied with statistical-mechanical theory and Brownian dynamics simulations. The particle dipole moments are initially perfectly aligned, and the magnetization is equal to its saturation value. The magnetization is then allowed to decay under zero-field conditions toward its equilibrium value of zero. The time dependence is predicted by solving the Fokker-Planck equation for the one-particle orientational distribution function. Interactions between particles are included by introducing an effective magnetic field acting on a given particle and arising from all of the other particles. Two different approximations are proposed and tested against simulations a first-order modified mean-field theory and a modified Weiss model. The theory predicts that the short-time decay is characterized by the Brownian rotation time τ_B, independent of the interaction strength. At times **** longer than τ_B, the asymptotic decay time is predicted to grow with increasing interaction strength. These predictions are borne out by the simulations. The modified Weiss model gives the best agreement with simulation, and its range of validity is limited to moderate, but realistic, values of the dipolar coupling constant.We study the double ionization of atoms subjected to circularly polarized (CP) laser pulses. We analyze two fundamental ionization processes the sequential (SDI) and nonsequential (NSDI) double ionization in the light of the rotating frame (RF) which naturally embeds nonadiabatic effects in CP pulses. https://www.selleckchem.com/products/thioflavine-s.html We use and compare two adiabatic approximations The adiabatic approximation in the laboratory frame (LF) and the adiabatic approximation in the RF. The adiabatic approximation in the RF encapsulates the energy variations of the electrons on subcycle timescales happening in the LF and this, by fully taking into account the ion-electron interaction. This allows us to identify two nonadiabatic effects including the lowering of the threshold intensity at which over-the-barrier ionization happens and the lowering of the ionization time of the electrons. As a consequence, these nonadiabatic effects facilitate over-the-barrier ionization and recollision-induced ionizations. We analyze the outcomes of these nonadiabatic effects on the recollision mechanism. We show that the laser envelope plays an instrumental role in a recollision channel in CP pulses at the heart of NSDI.We show that similarly to the logarithmic mean-velocity profile in wall-bounded turbulence, the landscape topography presents an intermediate region with a logarithmic mean-elevation profile. Such profiles are present in complex topographies with channel branching and fractal river networks resulting from model simulation, controlled laboratory experiments, and natural landscapes. Dimensional and self-similarity arguments are used to corroborate this finding. We also tested the presence of logarithmic profiles in discrete, minimalist models of networks obtained from optimality principles (optimal channel networks) and directed percolation. The emergence of self-similar scaling appears as a robust outcome in dynamically different, but spatially bounded, complex systems, as a dimensional consequence of length-scale independence.The efficiency of a displacement is the fraction of applied work over the change in free energy. This displacement efficiency is essential for linking wettability to applied work during displacement processes. We quantify the efficiency of slow immiscible displacements in porous media from pore space geometry. For this end, we introduce pore-scale definitions for thermodynamically reversible (ison) and irreverisble (rheon) processes. We argue that the efficiency of slow primary displacement is described by the geometry of the pore space for porous media with a sufficient number of pore bodies. This article introduces how to calculate such geometry-based efficiency locally, and integrating this local efficiency over the pore space yields an aggregate efficiency for the primary displacement in the porous medium. Further, we show how the geometrical characterization of the displacement efficiency links the efficiency to the constriction factor from transport processes governed by the Laplace equation. This enables estimation of displacement efficiency from traditional and widely available measurements for porous media.
We study periodic arrays of impurities that create localized regions of expansion, embedded in two-dimensional crystalline membranes. These arrays provide a simple elastic model of shape memory. As the size of each dilational impurity increases (or the relative cost of bending to stretching decreases), it becomes energetically favorable for each of the M impurities to buckle up or down into the third dimension, thus allowing for of order 2^M metastable surface configurations corresponding to different impurity "spin" configurations. With both discrete simulations and the nonlinear continuum theory of elastic plates, we explore the buckling of both isolated dilations and dilation arrays at zero temperature, guided by analogies with Ising antiferromagnets. We conjecture ground states for systems with triangular and square impurity superlattices, and comment briefly on the possible behaviors at finite temperatures.The phenomenology of Landau theory with spatial coupling through diffusion has been widely used in the study of phase transitions and patterning. Here we follow this theory and apply it to study theoretically and numerically continuous and discontinuous transitions to periodic spatial cellular patterns driven by lateral inhibition coupling. As opposed to diffusion, lateral inhibition coupling drives differences between adjacent cells. We analyze the appearance of errors in these patterns (disordered metastable states) and propose mechanisms to prevent them. These mechanisms are based on a temporal-dependent lateral inhibition coupling strength, which can be mediated, among others, by gradients of diffusing molecules. The simplicity and generality of the framework used herein is expected to facilitate future analyses of additional phenomena taking place through lateral inhibition interactions in more complex scenarios.We study dynamical signatures of quantum chaos in one of the most relevant models in many-body quantum mechanics, the Bose-Hubbard model, whose high degree of symmetries yields a large number of invariant subspaces and degenerate energy levels. The standard procedure to reveal signatures of quantum chaos requires classifying the energy levels according to their symmetries, which may be experimentally and theoretically challenging. We show that this classification is not necessary to observe manifestations of spectral correlations in the temporal evolution of the survival probability, which makes this quantity a powerful tool in the identification of chaotic many-body quantum systems.The dynamics of magnetization relaxation in ferrofluids are studied with statistical-mechanical theory and Brownian dynamics simulations. The particle dipole moments are initially perfectly aligned, and the magnetization is equal to its saturation value. The magnetization is then allowed to decay under zero-field conditions toward its equilibrium value of zero. The time dependence is predicted by solving the Fokker-Planck equation for the one-particle orientational distribution function. Interactions between particles are included by introducing an effective magnetic field acting on a given particle and arising from all of the other particles. Two different approximations are proposed and tested against simulations a first-order modified mean-field theory and a modified Weiss model. The theory predicts that the short-time decay is characterized by the Brownian rotation time τ_B, independent of the interaction strength. At times much longer than τ_B, the asymptotic decay time is predicted to grow with increasing interaction strength. These predictions are borne out by the simulations. The modified Weiss model gives the best agreement with simulation, and its range of validity is limited to moderate, but realistic, values of the dipolar coupling constant.We study the double ionization of atoms subjected to circularly polarized (CP) laser pulses. We analyze two fundamental ionization processes the sequential (SDI) and nonsequential (NSDI) double ionization in the light of the rotating frame (RF) which naturally embeds nonadiabatic effects in CP pulses. https://www.selleckchem.com/products/thioflavine-s.html We use and compare two adiabatic approximations The adiabatic approximation in the laboratory frame (LF) and the adiabatic approximation in the RF. The adiabatic approximation in the RF encapsulates the energy variations of the electrons on subcycle timescales happening in the LF and this, by fully taking into account the ion-electron interaction. This allows us to identify two nonadiabatic effects including the lowering of the threshold intensity at which over-the-barrier ionization happens and the lowering of the ionization time of the electrons. As a consequence, these nonadiabatic effects facilitate over-the-barrier ionization and recollision-induced ionizations. We analyze the outcomes of these nonadiabatic effects on the recollision mechanism. We show that the laser envelope plays an instrumental role in a recollision channel in CP pulses at the heart of NSDI.We show that similarly to the logarithmic mean-velocity profile in wall-bounded turbulence, the landscape topography presents an intermediate region with a logarithmic mean-elevation profile. Such profiles are present in complex topographies with channel branching and fractal river networks resulting from model simulation, controlled laboratory experiments, and natural landscapes. Dimensional and self-similarity arguments are used to corroborate this finding. We also tested the presence of logarithmic profiles in discrete, minimalist models of networks obtained from optimality principles (optimal channel networks) and directed percolation. The emergence of self-similar scaling appears as a robust outcome in dynamically different, but spatially bounded, complex systems, as a dimensional consequence of length-scale independence.The efficiency of a displacement is the fraction of applied work over the change in free energy. This displacement efficiency is essential for linking wettability to applied work during displacement processes. We quantify the efficiency of slow immiscible displacements in porous media from pore space geometry. For this end, we introduce pore-scale definitions for thermodynamically reversible (ison) and irreverisble (rheon) processes. We argue that the efficiency of slow primary displacement is described by the geometry of the pore space for porous media with a sufficient number of pore bodies. This article introduces how to calculate such geometry-based efficiency locally, and integrating this local efficiency over the pore space yields an aggregate efficiency for the primary displacement in the porous medium. Further, we show how the geometrical characterization of the displacement efficiency links the efficiency to the constriction factor from transport processes governed by the Laplace equation. This enables estimation of displacement efficiency from traditional and widely available measurements for porous media.
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