The development of a novel nanobiosorbent derived from waste molasses for the adsorptive removal of arsenic (As) has been attempted in this study. Waste molasses were chemically ameliorated through a solvothermal route for the incorporation of iron oxide, thereby producing iron oxide incorporated carbonaceous nanomaterial (IOCN). Synthesis of IOCN was confirmed through transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and atomic emission spectroscopy (AES) analysis. The surface area and porous behavior of IOCN were elucidated by Brunauer-Emmett-Teller (BET) assessments. The experimental conditions for adsorption were first modeled using response surface methodology (RSM) based on the central composite design (CCD), considering the parameters adsorbate dosage, adsorbent dosage, pH, and contact time. RSM optimizations were improved upon using a three-layer feed-forward multilayer perceptron (MLP) based Artificial Neural Network (ANN) model. Optimization through ANN model resulted in the increase of the maximal As adsorption efficiency to ~ 96% for IOCN. The IOCN isotherm plots show the best fit for the Sips isotherm, and the reaction kinetics follows the pseudo-second-order model, indicating the chemisorption mechanism for As adsorption. Evidence for direct coordination of As to the surface of adsorbents was further confirmed by FTIR spectroscopic studies before and after As adsorption. The high adsorption efficiencies and the low-cost facile synthesis of the IOCN nanosorbent from agro-industrial waste indicate their potential for commercial applications.The primary ecological effects of the eutrophication of upwelling in the nearshore waters are the triggering and sustenance of phytoplankton (diatom) blooms. Here, we present the changes in the morphological characteristics and body size of microautotrophs associated with the nutrient enrichment of coastal upwelling along the southwest coast of India. The FlowCAM data of microautotrophs representing two time series locations in the coastal environment along the southwest coast of India at 18 weekly/biweekly frequencies showed the following features. The most significant response of the microautotrophs to the eutrophication associated with coastal upwelling during the Southwest Monsoon (June-September) was an increase in their mean bio-volume, either by increasing the individual cell size or by forming large colonies. During the Southwest Monsoon, large colonies of Thalassiosira (~ 8 cells/colony), Thalassionema (> 16 cells/colony), and Asterionellopsis (> 8 cells/colony) become very abundant. Streptotheca formed large mat-like colonies (av. 192350 ± 348 μm3/individual), and Fragilariopsis grew as very long ribbons (av. 272997 ± 5071 μm3/individual). Large-sized Chaetoceros (av. 45715 ± 1273 μm3/individual) with longer setae were also plentiful during the Southwest Monsoon. All these changes in the morphology and life forms of microautotrophs would help them to rapidly assimilate nitrate under turbulent conditions during the Southwest Monsoon.Medium-flow atmospheric samplers were used to collect particulate (PM2.5) and gaseous samples from the indoor kitchen of each of 35 randomly selected rural houses in North China while a meal was being cooked. The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) and 9 nitro-PAHs (NPAHs) in the samples were quantified by high-performance liquid chromatography (HPLC). This study provided the real PAH and NPAH pollution characteristics and carcinogenic risk produced by cooking in rural indoor kitchens in North China. The mean PAH and NPAH concentrations in air in the indoor kitchens during cooking periods were 4049.1 and 1741.6 ng/m3, respectively. The PAH and NPAH concentrations were lower in the particulate phase than the gaseous phase. The mean PAH and NPAH concentrations were much higher for cooking using coal than for cooking using liquefied petroleum gas (LPG) or electricity. The PAH and NPAH benzo[a]pyrene toxic equivalent (TEQBaP) concentrations for cooking using coal were 1823.3 and 2760.9 ng/m3, respectively. Lower PAH and NPAH concentrations were found in kitchens with than without range hoods. Range hoods decreased the PAH and NPAH TEQBaP concentrations by 68.8% and 61.9%, respectively. Appropriate fuel and ventilation choice will improve air pollution in indoor kitchens during cooking. The results provide important evidence for changing cooking habits and developing policies for cooking in rural China.The transportation sector is one of the important energy consumption and carbon emission sources. This paper extends the multi-directional efficiency analysis (MEA) to zero-sum game MEA (ZSG-MEA) with considering the CO2 emission as a fixed-sum undesirable output to measure the energy and environmental performance (EEP) of the transportation sector. The ZSG-MEA window analysis is applied to dynamically evaluate the EEP of China's transportation sector in 30 provincial-level regions during 2008-2017. Some interesting findings are obtained (i) the EEP of the transportation sector in most regions has not been performed well but the average EEP of the transportation sector in most regions has been gradually improved since 2011. A general trend is that the transportation sector in the east area wins the best average EEP, and the average EEP of the central area is better than that of the west area, but their gap is narrowing from 2012. (ii) The EEP fluctuation verifies the greatest imbalance of EEP among the east area's regions. Both the east area and the central area are narrowing the imbalance in recent years, but the west area has an inverse trend. https://www.selleckchem.com/products/pqr309-bimiralisib.html (iii) The performance of CO2 emissions is better than that of energy consumption in all three areas, which implies that China's transportation sector seems to have paid more attention on emission reduction than energy conservation. Besides, the east area has the best performance of energy consumption and CO2 emissions from an overall perspective. And the energy consumption and CO2 emissions in the central area perform better than the west area before 2013, but then shows an entangled state from 2013. (iv) From the average variable specific ZSG-MEA efficiency, the industrial added value of transportation sector performs better than other variables in the east area and central area, but the situation in the west area is inverse. Some useful insights are provided according to these findings.