Sunflower oil-in-water Pickering emulsions were fabricated using octenyl succinic anhydride modified rice starches as particulate stabilizers. The major factors influencing oxidative stability of emulsions were investigated. Results indicated that oxidative stability was enhanced with the increase of starch particle concentration and oil fractions. The emulsions had excellent oxidative stability at pH 6.0-7.0. Low NaCl concentration of 40 mmol/L slightly increased lipid stability, while high NaCl concentration decreased oxidative stability. Sucrose concentrations ranging from 0 to 200 mmol/L had no obvious effect on oxidative stability. Results of confocal laser scanning microscope showed that the hydrophobically modified starch particles built up 3D-network barrier around oil droplets at oil-water interface, which increased the viscosity of continuous phase and prevented oil droplets from contacting with pro-oxidants in water phase, thus decreasing peroxide value and thiobarbituric acid reactive substances. These results implied that starch-based Pickering emulsion may be a promising delivery vehicle for bioactive compounds.Conventional isolation of chitin from crustacean waste demands the use of high amounts of hazardous chemicals, hence not leading to a sustainable process. Atmospheric-pressure dielectric barrier discharge (DBD) plasma has demonstrated an enhanced ability to remove proteins directly from the biomass without the formation of any waste. Simultaneously, organic acids have proven very efficient in the removal of inorganic minerals from crustacean waste. Therefore, a hybrid process composed of DBD plasma and demineralization using organic acids has been successfully applied for the isolation of chitin. Results showed that the integration of nitrogen-based plasma and lactic acid demineralization allowed the elimination of 90 % of the proteins and ensures the complete removal of minerals from shrimp shells waste. The isolated chitin was further characterized using distinct techniques, namely XPS, ATR-FTIR, XRD and SEM. Chitin degree of deacetylation and molecular weight were also assessed. Hence, this work presents a sustainable and feasible platform for the extraction and purification of chitin from crustacean waste with almost zero waste formed.Enzymes are proteins specialized in catalyzing biological reactions. However, factors such as cost and operational limitations could limit their applications in the industrial sector. An alternative to these limiting factors is enzyme immobilization, which enables reuse and increases biocatalyst stability. Cellulose can be employed in enzyme immobilization, and is an outstanding alternative due to availability and cost. Additionally, this material might undergo several chemical treatments, thus obtaining cellulose nanocrystals and nanofibers. The use of nanomaterials at an industrial scale requires more refined unit operations to separate them, a setback that can be solved by combining these materials to magnetic nanoparticles. This review shows important aspects for the synthesis and application of nanocellulose and magnetic nanoparticles. It also reports new trends and strategies to associate these materials. Magnetic cellulose is a versatile support for enzyme immobilization, so **** so that different immobilization methods might be conducted using this material.Alginate is a commercially important polysaccharide widely applied in various industries. Carbohydrate-binding proteins could be utilized as desirable tools in the investigation and further applications of polysaccharides. Few alginate-binding proteins have hitherto been characterized and reported. In the present study, a novel alginate-binding protein ABP_Wf, consisting of two "orphan" carbohydrate-binding modules, was cloned from a predicted alginate utilization locus of marine bacterium Wenyingzhuangia funcanilytica, and expressed in Escherichia coli. ABP_Wf exhibited a specific binding capacity to alginate, and the association constant (Ka) and affinity (KD) were 1.94 × 103 M-1s-1 and 1.16 × 10-6 M. It was confirmed that the binding capacity of ABP_Wf to alginate is attributed to its constituent CBM16 domain rather than the CBM44 domain. The potentials of ABP_Wf in the semi-quantitative detection and the in situ visualization of alginate were evaluated, which implied that ABP_Wf could be served as a promising tool for investigating alginate.A smart hydrogel with pH/magnetic dual sensitivity was synthesized by in-situ synthesis of Fe3O4 inside carboxymethyl chitin hydrogel matrix prepared from Hericium erinaceus residue. The structure, pH/magnetic sensitivity, swelling and drug release behavior of the prepared hydrogels were investigated. The results showed that Fe3O4 nanoparticles were successfully synthesized and uniformly distributed within the hydrogels. The prepared hydrogels could be attracted by the magnet and exhibited sustained shrinkage behavior at low pH, with the desirable pH/magnetic sensitivity. The formed Fe3O4 could be developed inside the hydrogels by increasing the concentrations of precursor Fe2+/Fe3+ ions, and the magnetic sensitivity of hydrogels was enhanced, while the pH sensitivity and swelling degree were weakened. The Fe3O4 content-dependent behavior of the prepared hydrogels suggested the adjustable properties of hydrogels. The release of 5-Fu in simulated gastric and intestinal fluids followed the Fick diffusion mechanism and showed different release rates, indicating the pH-controlled drug release behavior.The present study reports the successful synthesis of the flame-retardant and smoke-suppressant flexible polyurethane foam (FPUF) through a fully bio-based coating. Hydroxyapatite (HAP) is added to the solutions containing sodium alginate (SA) and chitosan (CH), respectively, to create negative and positive polyelectrolytes for Layer-by-Layer (LbL) assembly. The influence of the solution concentrations and bilayers numbers deposited on the flame-retardant and mechanical properties of FPUF samples is investigated systematically. https://www.selleckchem.com/products/tucidinostat-chidamide.html Benefitting from the presence of such a fully bio-based coating, the resultant FPUF affords excellent smoke-suppressant and flame-retardant features. In particular, the FPUF coated by 9 bilayers of HAP-SA/HAP-CH exhibits significantly declined peak heat release rate, total release rate and smoke production release by 77.7 %, 56.5 % and 53.8 %, respectively. The compression test verifies the coated FPUFs exhibit lower recovery properties compared with the uncoated one. These results demonstrate that a green and cost-effective strategy is provided for producing flame-retardant, anti-dripping and smoke-suppressant FPUFs.
Sunflower oil-in-water Pickering emulsions were fabricated using octenyl succinic anhydride modified rice starches as particulate stabilizers. The major factors influencing oxidative stability of emulsions were investigated. Results indicated that oxidative stability was enhanced with the increase of starch particle concentration and oil fractions. The emulsions had excellent oxidative stability at pH 6.0-7.0. Low NaCl concentration of 40 mmol/L slightly increased lipid stability, while high NaCl concentration decreased oxidative stability. Sucrose concentrations ranging from 0 to 200 mmol/L had no obvious effect on oxidative stability. Results of confocal laser scanning microscope showed that the hydrophobically modified starch particles built up 3D-network barrier around oil droplets at oil-water interface, which increased the viscosity of continuous phase and prevented oil droplets from contacting with pro-oxidants in water phase, thus decreasing peroxide value and thiobarbituric acid reactive substances. These results implied that starch-based Pickering emulsion may be a promising delivery vehicle for bioactive compounds.Conventional isolation of chitin from crustacean waste demands the use of high amounts of hazardous chemicals, hence not leading to a sustainable process. Atmospheric-pressure dielectric barrier discharge (DBD) plasma has demonstrated an enhanced ability to remove proteins directly from the biomass without the formation of any waste. Simultaneously, organic acids have proven very efficient in the removal of inorganic minerals from crustacean waste. Therefore, a hybrid process composed of DBD plasma and demineralization using organic acids has been successfully applied for the isolation of chitin. Results showed that the integration of nitrogen-based plasma and lactic acid demineralization allowed the elimination of 90 % of the proteins and ensures the complete removal of minerals from shrimp shells waste. The isolated chitin was further characterized using distinct techniques, namely XPS, ATR-FTIR, XRD and SEM. Chitin degree of deacetylation and molecular weight were also assessed. Hence, this work presents a sustainable and feasible platform for the extraction and purification of chitin from crustacean waste with almost zero waste formed.Enzymes are proteins specialized in catalyzing biological reactions. However, factors such as cost and operational limitations could limit their applications in the industrial sector. An alternative to these limiting factors is enzyme immobilization, which enables reuse and increases biocatalyst stability. Cellulose can be employed in enzyme immobilization, and is an outstanding alternative due to availability and cost. Additionally, this material might undergo several chemical treatments, thus obtaining cellulose nanocrystals and nanofibers. The use of nanomaterials at an industrial scale requires more refined unit operations to separate them, a setback that can be solved by combining these materials to magnetic nanoparticles. This review shows important aspects for the synthesis and application of nanocellulose and magnetic nanoparticles. It also reports new trends and strategies to associate these materials. Magnetic cellulose is a versatile support for enzyme immobilization, so much so that different immobilization methods might be conducted using this material.Alginate is a commercially important polysaccharide widely applied in various industries. Carbohydrate-binding proteins could be utilized as desirable tools in the investigation and further applications of polysaccharides. Few alginate-binding proteins have hitherto been characterized and reported. In the present study, a novel alginate-binding protein ABP_Wf, consisting of two "orphan" carbohydrate-binding modules, was cloned from a predicted alginate utilization locus of marine bacterium Wenyingzhuangia funcanilytica, and expressed in Escherichia coli. ABP_Wf exhibited a specific binding capacity to alginate, and the association constant (Ka) and affinity (KD) were 1.94 × 103 M-1s-1 and 1.16 × 10-6 M. It was confirmed that the binding capacity of ABP_Wf to alginate is attributed to its constituent CBM16 domain rather than the CBM44 domain. The potentials of ABP_Wf in the semi-quantitative detection and the in situ visualization of alginate were evaluated, which implied that ABP_Wf could be served as a promising tool for investigating alginate.A smart hydrogel with pH/magnetic dual sensitivity was synthesized by in-situ synthesis of Fe3O4 inside carboxymethyl chitin hydrogel matrix prepared from Hericium erinaceus residue. The structure, pH/magnetic sensitivity, swelling and drug release behavior of the prepared hydrogels were investigated. The results showed that Fe3O4 nanoparticles were successfully synthesized and uniformly distributed within the hydrogels. The prepared hydrogels could be attracted by the magnet and exhibited sustained shrinkage behavior at low pH, with the desirable pH/magnetic sensitivity. The formed Fe3O4 could be developed inside the hydrogels by increasing the concentrations of precursor Fe2+/Fe3+ ions, and the magnetic sensitivity of hydrogels was enhanced, while the pH sensitivity and swelling degree were weakened. The Fe3O4 content-dependent behavior of the prepared hydrogels suggested the adjustable properties of hydrogels. The release of 5-Fu in simulated gastric and intestinal fluids followed the Fick diffusion mechanism and showed different release rates, indicating the pH-controlled drug release behavior.The present study reports the successful synthesis of the flame-retardant and smoke-suppressant flexible polyurethane foam (FPUF) through a fully bio-based coating. Hydroxyapatite (HAP) is added to the solutions containing sodium alginate (SA) and chitosan (CH), respectively, to create negative and positive polyelectrolytes for Layer-by-Layer (LbL) assembly. The influence of the solution concentrations and bilayers numbers deposited on the flame-retardant and mechanical properties of FPUF samples is investigated systematically. https://www.selleckchem.com/products/tucidinostat-chidamide.html Benefitting from the presence of such a fully bio-based coating, the resultant FPUF affords excellent smoke-suppressant and flame-retardant features. In particular, the FPUF coated by 9 bilayers of HAP-SA/HAP-CH exhibits significantly declined peak heat release rate, total release rate and smoke production release by 77.7 %, 56.5 % and 53.8 %, respectively. The compression test verifies the coated FPUFs exhibit lower recovery properties compared with the uncoated one. These results demonstrate that a green and cost-effective strategy is provided for producing flame-retardant, anti-dripping and smoke-suppressant FPUFs.
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