Because of the limited space and high cost of offshore platforms, the dispersion and dissolution of the polymer are required to be of high efficiency, which is essential for polymer injection to enhance hydrocarbon recovery. The numerical simulation models of the water-powder mixing process by Venturi jetting and air-mixing were established. The multiphase flow fields in the water jet ejector, water-powder mixing head, and stirring tank were numerically simulated by FLUENT. Then, the distributions of velocity, volume fraction, pressure, and turbulent kinetic energy of each phase were obtained to evaluate the effects of polymer dispersion and the dissolution of the two mixing methods. According to the maximum velocity of the mixture at the Venturi jet, the optimized length of the throat is 25 mm in our models. The results of the air-mixing process show that a 120° angle of support rods has the best effect of water-powder mixing. The results of the present study show that compared with air-mixing, the combination of Venturi jet and the stirring tank can obtain a broader agitation range and more extensive effect on the flow field, which could uniformly disperse the polymer powder into water. This study has a guiding significance for the design of the onsite polymer injection process.In this work, copper selenide (Cu3Se2 umangite phase) was synthesized by two routes, using a chemical reaction and the hydrothermal method to obtain CuSe-A and CuSe-H, respectively. The synthesis of Cu3Se2 consisted of a three-step process in the first step, copper(I) oxide hexapods (Cu2O) were obtained as the copper reservoir; in the second step, selenium ions were obtained from the reduction of selenium powder; and in the third step involves mixing two precursors following the two synthesis routes mentioned before. Analysis of X-ray diffraction and X-ray photoelectron spectroscopy showed the formation of the Cu3Se2 phase by both synthesis routes. On the other hand, using the scanning electron microscopy (SEM) technique, it is observed that the Cu3Se2 sample (CuSe-A) is obtained by exchanging in solution with agitation and that the copper selenium phase grows only on the surface of the hexapods. Meanwhile, the hydrothermal route promotes a total conversion of copper(I) oxide hexapods to the copper selenide phase (CuSe-H). The resulting materials were tested as photocatalytic materials to remove methylene blue dye in water under sunlight irradiation. Cu3Se2 (CuSe-H) obtained by the hydrothermal route exhibited a higher efficiency of photodegradation of dye, reaching a removal percentage of 92% after 4 h under sunlight.To investigate liquid seepage process in a coal granular-type porous medium, a new sampling device was designed to obtain coal samples with required porosity. Meanwhile, an approach combining ultra-deep-field microscopy with advanced digital image processing technologies was proposed to rebuild granular-type porous medium models. The liquid seepage process was simulated with CFD, and the effects of head pressure, liquid viscosity, and pore size were studied. The results show that only liquids with head pressures above a critical value can penetrate into coal stacks and the hydraulic conductivity and permeability are positively correlated to the driving head pressure. Liquid viscosity enhances flow deformation, causing more eddy current energy dissipation; the turbulent eddy dissipation caused by acetone, methanol, and ethanol was 700, 1200, and 4700 m2/s3, respectively. Larger pores can strengthen the additional pressure at the front end of the flow, reducing the flow resistance and thus increasing the fluid kinetic energy and seepage velocity.The corrosive environment in sulfur-containing equipment is often complicated and changeable. This study adopted the Taguchi method to optimize the immersion test, and the L27(313) orthogonal table was used to design an immersion corrosion experiment. The influence of four factors, namely, the total acid number (TAN), sulfur, chlorine, and water, on the corrosion of AISI 1020 in the oil phase was studied. It showed that the effect of chlorine is the most pronounced and that of sulfur is second followed by that of the TAN and H2O. It was also found that the effect of H2O exceeds that of the TAN after 336 h; meanwhile, the interaction between the four factors varies over time and stabilizes after 336 h. Moreover, corrosion rate curves reveal that the stable corrosion product film formed on the metal surface gradually slows down the corrosion process. Analysis of corrosion morphology and product composition was done by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Overall, the synergistic effect of the corrosion rate changing with time provides a certain reference for the corrosion protection of sulfur-containing storage equipment.Catalytic fast co-pyrolysis of biomass and plastic is an effective method to achieve high-quality bio-oil production. In this work, (Ni)-MCM-41 catalysts with different Ni loadings were prepared and characterized in detail by using a variety of advanced analytical techniques, and the effects on the catalytic performance were analyzed by micropyrolysis with gas chromatography mass spectrometry (Py-GC/MS) and thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR) methods. The results showed that an appropriate amount of Ni addition can effectively modulate the physicochemical properties of MCM-41. For a Ni loading of 25.1 wt % (Cat-C), the catalyst showed an optimal catalytic performance, a decrease in the proportion of oxygenated compounds in the product from 35.6 (MCM-41) to 13.4%, and an increase in the relative total amount of olefins plus aromatics from 62.2 (MCM-41) to 84.6%. The excellent catalytic performance of Cat-C can be ascribed to a balancing of its proper physical structural properties, appropriate acidity, strong metal-carrier interaction, high metal dispersion, and excellent compatibility balance between active and acidic sites.A PEG1000-modified nickel-based catalyst (Ni-PEG1000/FC3R) supported on an activated fluid catalytic cracking catalyst residue (FC3R) was synthesized and applied to C9 petroleum resin (C9PR) hydrogenation. The results of the Brunauer-Emmett-Teller method, X-ray diffraction, H2 temperature-programmed reduction, and scanning electron microscopy-energy-dispersive X-ray spectroscopy show that the Ni-PEG1000/FC3R catalyst had a smaller crystallite size and higher Ni dispersion than those of a Ni/FC3R catalyst. The prepared Ni-PEG1000/FC3R catalyst was applied in a hydrogenation of C9PR at 270 °C and 6 MPa H2 pressure for 3 h. Under these conditions, the bromine value of C9PR was decreased from 46.1 g Br/100 g (Gardner color grade no. https://www.selleckchem.com/products/quinine-dihydrochloride.html 11) to 0.72 g Br/100 g (Gardner color grade no. 1), and the sulfur content was reduced from 25.7 to 1.66 mg kg-1. Experimental results show that the Ni-PEG1000/FC3R catalyst exhibited high activity and stability for C9PR hydrogenation.
Because of the limited space and high cost of offshore platforms, the dispersion and dissolution of the polymer are required to be of high efficiency, which is essential for polymer injection to enhance hydrocarbon recovery. The numerical simulation models of the water-powder mixing process by Venturi jetting and air-mixing were established. The multiphase flow fields in the water jet ejector, water-powder mixing head, and stirring tank were numerically simulated by FLUENT. Then, the distributions of velocity, volume fraction, pressure, and turbulent kinetic energy of each phase were obtained to evaluate the effects of polymer dispersion and the dissolution of the two mixing methods. According to the maximum velocity of the mixture at the Venturi jet, the optimized length of the throat is 25 mm in our models. The results of the air-mixing process show that a 120° angle of support rods has the best effect of water-powder mixing. The results of the present study show that compared with air-mixing, the combination of Venturi jet and the stirring tank can obtain a broader agitation range and more extensive effect on the flow field, which could uniformly disperse the polymer powder into water. This study has a guiding significance for the design of the onsite polymer injection process.In this work, copper selenide (Cu3Se2 umangite phase) was synthesized by two routes, using a chemical reaction and the hydrothermal method to obtain CuSe-A and CuSe-H, respectively. The synthesis of Cu3Se2 consisted of a three-step process in the first step, copper(I) oxide hexapods (Cu2O) were obtained as the copper reservoir; in the second step, selenium ions were obtained from the reduction of selenium powder; and in the third step involves mixing two precursors following the two synthesis routes mentioned before. Analysis of X-ray diffraction and X-ray photoelectron spectroscopy showed the formation of the Cu3Se2 phase by both synthesis routes. On the other hand, using the scanning electron microscopy (SEM) technique, it is observed that the Cu3Se2 sample (CuSe-A) is obtained by exchanging in solution with agitation and that the copper selenium phase grows only on the surface of the hexapods. Meanwhile, the hydrothermal route promotes a total conversion of copper(I) oxide hexapods to the copper selenide phase (CuSe-H). The resulting materials were tested as photocatalytic materials to remove methylene blue dye in water under sunlight irradiation. Cu3Se2 (CuSe-H) obtained by the hydrothermal route exhibited a higher efficiency of photodegradation of dye, reaching a removal percentage of 92% after 4 h under sunlight.To investigate liquid seepage process in a coal granular-type porous medium, a new sampling device was designed to obtain coal samples with required porosity. Meanwhile, an approach combining ultra-deep-field microscopy with advanced digital image processing technologies was proposed to rebuild granular-type porous medium models. The liquid seepage process was simulated with CFD, and the effects of head pressure, liquid viscosity, and pore size were studied. The results show that only liquids with head pressures above a critical value can penetrate into coal stacks and the hydraulic conductivity and permeability are positively correlated to the driving head pressure. Liquid viscosity enhances flow deformation, causing more eddy current energy dissipation; the turbulent eddy dissipation caused by acetone, methanol, and ethanol was 700, 1200, and 4700 m2/s3, respectively. Larger pores can strengthen the additional pressure at the front end of the flow, reducing the flow resistance and thus increasing the fluid kinetic energy and seepage velocity.The corrosive environment in sulfur-containing equipment is often complicated and changeable. This study adopted the Taguchi method to optimize the immersion test, and the L27(313) orthogonal table was used to design an immersion corrosion experiment. The influence of four factors, namely, the total acid number (TAN), sulfur, chlorine, and water, on the corrosion of AISI 1020 in the oil phase was studied. It showed that the effect of chlorine is the most pronounced and that of sulfur is second followed by that of the TAN and H2O. It was also found that the effect of H2O exceeds that of the TAN after 336 h; meanwhile, the interaction between the four factors varies over time and stabilizes after 336 h. Moreover, corrosion rate curves reveal that the stable corrosion product film formed on the metal surface gradually slows down the corrosion process. Analysis of corrosion morphology and product composition was done by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Overall, the synergistic effect of the corrosion rate changing with time provides a certain reference for the corrosion protection of sulfur-containing storage equipment.Catalytic fast co-pyrolysis of biomass and plastic is an effective method to achieve high-quality bio-oil production. In this work, (Ni)-MCM-41 catalysts with different Ni loadings were prepared and characterized in detail by using a variety of advanced analytical techniques, and the effects on the catalytic performance were analyzed by micropyrolysis with gas chromatography mass spectrometry (Py-GC/MS) and thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR) methods. The results showed that an appropriate amount of Ni addition can effectively modulate the physicochemical properties of MCM-41. For a Ni loading of 25.1 wt % (Cat-C), the catalyst showed an optimal catalytic performance, a decrease in the proportion of oxygenated compounds in the product from 35.6 (MCM-41) to 13.4%, and an increase in the relative total amount of olefins plus aromatics from 62.2 (MCM-41) to 84.6%. The excellent catalytic performance of Cat-C can be ascribed to a balancing of its proper physical structural properties, appropriate acidity, strong metal-carrier interaction, high metal dispersion, and excellent compatibility balance between active and acidic sites.A PEG1000-modified nickel-based catalyst (Ni-PEG1000/FC3R) supported on an activated fluid catalytic cracking catalyst residue (FC3R) was synthesized and applied to C9 petroleum resin (C9PR) hydrogenation. The results of the Brunauer-Emmett-Teller method, X-ray diffraction, H2 temperature-programmed reduction, and scanning electron microscopy-energy-dispersive X-ray spectroscopy show that the Ni-PEG1000/FC3R catalyst had a smaller crystallite size and higher Ni dispersion than those of a Ni/FC3R catalyst. The prepared Ni-PEG1000/FC3R catalyst was applied in a hydrogenation of C9PR at 270 °C and 6 MPa H2 pressure for 3 h. Under these conditions, the bromine value of C9PR was decreased from 46.1 g Br/100 g (Gardner color grade no. https://www.selleckchem.com/products/quinine-dihydrochloride.html 11) to 0.72 g Br/100 g (Gardner color grade no. 1), and the sulfur content was reduced from 25.7 to 1.66 mg kg-1. Experimental results show that the Ni-PEG1000/FC3R catalyst exhibited high activity and stability for C9PR hydrogenation.
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