This study performed continuous measurements of 105 volatile organic compounds (VOCs) in Weinan in the eastern Guanzhong Plain from 1 July to September 19, 2019. Ozone (O3) episode and non-episode days were identified according to China Ambient Air Quality Standard, and the concentrations of total quantified VOCs (TVOCs) were 33.43 ± 13.64 ppbv and 29.13 ± 14.31 ppbv, respectively. During different O3 pollution episodes, alkanes comprised the highest proportion to TVOC concentrations, while alkenes contributed the most to ozone formation potential (OFP). In addition, O3 episode days were mainly caused by enhanced emissions of precursors and meteorological conditions favorable to O3 production. Based on Empirical Kinetic Modelling Approach (EKMA), the O3 formation in Weinan was found in the transitional regime, in which the synergistic reduction of VOCs and nitrogen oxide (NOx) would be more effective for O3 reduction. Eight sources were identified by positive matrix factorization (PMF) model, with natural gas (NG)/liquefied petroleum gas (LPG) usage as the most significant contributor to VOC concentration, followed by vehicle exhaust, biomass burning, solvent usage, fuel evaporation, rubber/plastic industrial emissions, biogenic source, and mixed industrial emissions. Furthermore, rubber/plastic industrial emissions, solvent usage, fuel evaporation, and vehicle exhaust were the most significant sources to O3 formation. Based on conditional bivariate probability function (CBPF), vehicle exhaust, fuel evaporation, and solvent usage were mainly local emissions, while other sources were mainly affected by regional transport. This study provides useful reference for research on the atmospheric photochemical formation of O3 and evidence for regional O3 reduction strategies.This paper presents the results of the research on the influence of catalytic activity of iron(II) octacarboxyphthalocyanines (FePcOC) on the transformation of diclofenac (DCF) which is the most popular anti-inflammatory analgesic. Diclofenac poses a serious threat to the natural environment. The paper demonstrates that diclofenac, in the presence a monomeric form of iron octacarboxyphthalocyanine and hydroxyl radicals (HO•) (from H2O2), undergoes a transformation into diclofenac-2,5-iminoquinone (DCF-2,5-IQ), causing distinct changes in the UV-Vis absorption spectrum. In the presence of iron octacarboxyphthalocyanine and H2O2, the previously colourless diclofenac solution becomes intense orange. As a result, a new band at approx. 450 nm appears in the absorption spectrum. HPLC analysis has shown that the concentration of diclofenac decreases with time. TD-DFT calculations using the CAM-B3LYP/6-31+G (d, p) method have been conducted to confirm experimental data concerning the formation of a new band at λmax = 450 nm.The abuse of antibiotics has brought out serious bacterial resistance, which threatens the ecological environment and human health. Quorum sensing inhibitors (QSIs), as a new kind of potential antibiotic substitutes that are theoretically difficult to trigger bacterial resistance, are recommended to individually use or jointly use with traditional antibiotics. However, there are few studies on the resistance risk in the use of QSIs. In this study, the influence of QSIs alone or in combination with sulfonamides (SAs) on conjugative transfer and mutation of Escherichia coli (E. coli) was investigated to explore whether QSIs have the potential to induce bacterial resistance. The results show that QSIs may facilitate plasmid RP4 conjugative transfer by binding with SdiA protein to regulate pilus expression, and interact with LsrR protein to increase SOS gene expression, inducing gene mutation. The QSIs-SAs mixtures could promote plasmid RP4 conjugative transfer and mutation in E. coli, and the main joint effects are synergism and antagonism. Furthermore, there is a good correlation among conjugative transfer, mutation, and growth inhibition of QSIs-SAs to E. coli. It could be speculated that bacteria may delay cell division to provide sufficient energy and time for regulating conjugative transfer and mutation under the stress of QSIs and their combined exposure with antibiotics, which is essentially a balance between bacterial resistance and toxicity. This study provides a reference for the resistance risk assessment of QSIs and benefits the clinical application of QSIs.How to effectively bioremediate aquacultural wastewater using microbes is an urgent issue for the application of aquaculture beneficial microorganisms. Purple non-sulfur bacteria (PNSB) are beneficial in preventing related pollution in aquaculture applications. An autochthonous PNSB Rhodobacter sphaeroides was employed in this study to explore an effective bioremediation strategy of aquacultural wastewater. The test bacterium showed high performance in the removal of ammonium (97.50% ± 0.78% of 42 mg L-1 NH4+-N) and phosphate (93.24% ± 0.71% of 50 mg L-1 PO43--P) in the synthetic wastewater, which are the two crucial indicators of the aquacultural wastewater bioremediation. The study also unveiled that the imbalanced ratio of nutrients in water was the principal reason for limiting the efficient bioremediation of shrimp-culture wastewater. Therefore, an effective microbial bioremediation strategy was proposed by comprehensively considering bacterial pollutant metabolism kinetics constants such as specific consumption yields of chemical oxygen demand (COD)/phosphorous and nitrogen/phosphorous. Finally, COD, total nitrogen (TN), total phosphorus (TP), and ammonium (NH4+-N) in the wastewater were examined, and the results showed that they all decreased to the acceptable values. In conclusion, this study suggested a novel method for improved bioremediation efficiency of aquacultural wastewater, and the findings revealed that this strategy is promising due to its characteristics to be used in various aquaculture wastewater types.Metal oxide anode electrocatalysts are important for an effective removal of contaminants and the enhancement of electrode durability in the electrochemical oxidation process. https://www.selleckchem.com/products/marimastat.html Herein, we report the enhanced lifetime of RuOx-TiO2 composite anodes that was achieved by optimizing the fabrication conditions (e.g., the Ru mole fraction, total metal content, and calcination time). The electrode durability was assessed through accelerated service lifetime tests conducted under harsh environmental conditions, by using 3.4% NaCl and 1.0 A/cm2. The electrochemical characteristics of the anodes prepared with metal oxides having different compositions were evaluated using cyclic voltammetry, electrochemical impedance spectroscopy, and X-ray analyses. We noticed that, the larger the Ru mole fraction, the more durable were the electrodes. The RuOx-TiO2 electrodes were found to be highly stable when the Ru mole fraction was >0.7. The 0.8RuOx-0.2TiO2 electrode was selected as the one with the most appropriate composition, considering both its stability and contaminant treatability.