The assembly of cellulose nanocrystals (CNCs) that produce attractive structural color shows great potential in anti-counterfeiting application, but their processability and recyclability remain unsatisfactory due to the strong hydrogen bonds between CNCs. For the first time, optical anti-counterfeiting patterns are obtained by additive printing of surface-functionalized CNC inks (CNC-DC5700-NPES). The surface-functionalized CNC inks are prepared by sequential modification of CNCs with organosilane (DC5700) and polyoxyethylene ether (NPES), which show good flowability under shearing force and transform into a gel-like phase rapidly after printing, making possible ink-jet printing without additives. The printed patterns are transparent under natural light but show vivid interference color, showing anti-counterfeiting features between crossed polarizers. The texture and optical properties of the printed patterns can be facilely controlled by tuning the printing parameters, such as nozzle diameter, writing angle, and filling width. Moreover, the CNC-DC5700-NPES patterns with a core-shell structure could be collected in various solvents and reprinted after removing solvents. This work provided a new pathway for the preparation of optical anti-counterfeiting patterns from biomass resources.Immature grain represents a precious nutritional source in many rural Africa areas. To optimize processing of immature rice into pepeta (a traditional rice-flakes produced from immature rice grains), immature rice (TXD306 variety) harvested at 18 and 26 days after 50% heading were processed in the laboratory under different soaking (0 and 12 h) and roasting temperature (80, 100 and 120 °C) regimes. Riboflavin, nicotinic acid, nicotinamide and iron concentration increased with severity of roasting temperature, while thiamine has an opposite trend. Heating promoted the transformation of insoluble into soluble dietary fiber, increased lipid digestibility decreasing protein one, which showed the highest value when rice was roasted at 100 °C. Soaking before roasting significantly increased moisture and iron content while slightly increased riboflavin, nicotinic acid and nicotinamide when compared to unsoaked products. Among roasted products, starch digestibility increased with roasting temperature. Microstructure analysis indicated a complete loss of cell wall integrity in cooked rice, determining a complete starch and protein digestion while this is delayed in raw rice and roasted products. We concluded that roasting at 100 °C is the optimum temperature to produce pepeta of the highest protein digestibility and low starch digestibility. Soaking before roasting at 120 °C is best when retaining micronutrients is considered.This work describes a method to create dynamic pre-programmed surface textures by an alternating electric field on coatings that consist of a silicon oxide reinforced viscoelastic siloxane network. The finite element method is developed to predict the complex deformation figures and time-resolved experimental topographical surface analysis is used to confirm them.High molecular weight polymers are used in industrially important applications where the polymers adsorb onto surfaces of inorganic particles and facilitate dispersion, stabilization or flocculation of formulations. https://www.selleckchem.com/products/sb273005.html The surface conformation of these adsorbed polymers is key to their performance, yet an understanding of the effects of polymer charge, concentration and molecular weight on polymer conformation is incomplete. Here the adsorption behavior of high molecular weight, non-ionic, polyethylene oxide (PEO) and anionic partially hydrolyzed polyacrylamide (HPAM) polymers to a model clay, LAPONITE® (a trademark of BYK Additives, Inc.), was studied by small angle neutron scattering over a range of polymer concentrations. The adsorption of PEO was dependent on polymer concentration at all molecular weights, first adsorbing onto the radial edge of the clay particles and then to the clay faces as polymer concentration increased. While similar behavior was observed at low concentrations of HPAM, above a critical concentration, HPAM desorption results in large clay aggregates, which decrease in size at higher polymer loadings. The difference in adsorption properties as a function of polymer charge and concentration is interpreted in terms of conformational differences of adsorbed polymer at the clay surface. Changes in the volume fraction of adsorbed PEO with polymer concentration indicate changes in the relative amounts of adsorbed chain segments in trains, loops and tails, with no clay aggregation. In contrast, a constant volume fraction of adsorbed HPAM at low concentrations gives way to desorption at higher concentration due to charge repulsion, and depletion aggregation of the clay.Co9S8 and transition metal hydroxides are both potential pseudo-capacitance electrode materials for supercapacitors. Co9S8 has a large specific capacitance and electrochemical activity, and transition metal hydroxides have the advantages of high capacitance and redox activity due to their multiple valence metals and open layered structure. In this study, Co9S8 and NiCoLDH are used to form a Co9S8-aCNT-NiCoLDH composite electrode material by twining acidified carbon nanotubes (aCNTs) around hollow Co9S8 rods and then compounding nickel cobalt hydroxide (NiCoLDH) on the outside. aCNTs provide more electronic channels, which bring more active electrochemical reactions and absorb the volume expansion of Co9S8. The hollow Co9S8 rods and flower-like NiCoLDH structures ensure that the electrode has a highly open structure, which increases the contact area with the electrolyte and is beneficial for ion transport. The outer NiCoLDH can also reduce the volume expansion of Co9S8. These advantages ensure the high specific capacitance and rate performance of the Co9S8-aCNT-NiCoLDH electrode material. Co9S8-aCNT-NiCoLDH was used as the positive material to fabricate asymmetric supercapacitors with attractive energy density and power density, which further proved its excellent electrochemical performance.Intramolecular charge transfer (ICT) fluorescence has been widely investigated and exploited in sensor molecules. However, steric effects on the ICT fluorescence properties have rarely been reported so far, although research in this area would promote an understanding of the basics of solvation. Herein, we report the detailed fluorescence properties of bis(trimethylsilyl)benzo[b]thiophene-1,1-dioxide (TMSBTO2) and its caged cyclophanes and non-cage isomers, which demonstrate ICT fluorescence in various solutions. The fluorescence band maxima for these benzo[b]thiophene-1,1-dioxides (BTO2s) showed a red-shift with increasing solvent polarity, confirming ICT fluorescence characteristics. The linearity of the Lippert-Mataga plots was confirmed for all ICT fluorescence measured in hexane, toluene, AcOEt, CH2Cl2, and EtOH. The slopes of the plots decreased in the following order TMSBTO2, non-cage isomers, and caged BTO2s. It is concluded that the Onsager radii for these BTO2s were increased in the abovementioned order, assuming that the difference in the dipole moments between the excited and ground states for these BTO2s was identical.