Motivated by developing a simple, accurate, and widely applicable approach to incorporate the finite barrier correction in analytical calculation of the escape rate, the reactive flux theory for finite barriers is proposed. For higher temperatures, instead of at the top of the barrier in the original reactive flux theory, the starting point of the trajectories of Brownian particles is removed into a position inside the potential well where the probability distribution can be regarded as an equilibrium one, and the potential barrier is replaced with an equivalent parabolic potential barrier. The equivalent potential barrier frequency can be obtained by two schemes. The population is also calculated more realistically for finite barriers. The theoretical method is tested by a Brownian particle moving in a cubic metastable potential and subjected to Gaussian white noise. The numerical simulation results confirm the approach satisfactorily until lower reduced barrier heights.Statistical mechanics is an important tool for understanding polymer electroelasticity because the elasticity of polymers is primarily due to entropy. However, a common approach for the statistical mechanics of polymer chains, the Gaussian chain approximation, misses key physics. By considering the nonlinearities of the problem, we show a strong coupling between the deformation of a polymer chain and its dielectric response, that is, its net dipole. When chains with this coupling are cross linked in an elastomer network and an electric field is applied, the field breaks the symmetry of the elastomer's elastic properties and, combined with electrostatic torque and incompressibility, leads to intrinsic electrostriction. Conversely, deformation can break the symmetry of the dielectric response, leading to volumetric torque and asymmetric actuation. Both phenomena have important implications for designing high-efficiency soft actuators and soft electroactive materials, and the presence of mechanisms for volumetric torque, in particular, can be used to develop higher degree of freedom actuators and to achieve bioinspired locomotion.We consider several limiting cases of the joint probability distribution for a random matrix ensemble with an additional interaction term controlled by an exponent γ (called the γ ensembles). The effective potential, which is essentially the single-particle confining potential for an equivalent ensemble with γ=1 (called the Muttalib-Borodin ensemble), is a crucial quantity defined in solution to the Riemann-Hilbert problem associated with the γ ensembles. It enables us to numerically compute the eigenvalue density of γ ensembles for all γ>0. We show that one important effect of the two-particle interaction parameter γ is to generate or enhance the nonmonotonicity in the effective single-particle potential. For suitable choices of the initial single-particle potentials, reducing γ can lead to a large nonmonotonicity in the effective potential, which in turn leads to significant changes in the density of eigenvalues. For a disordered conductor, this corresponds to a systematic decrease in the conductance with increasing disorder. This suggests that appropriate models of γ ensembles can be used as a possible framework to study the effects of disorder on the distribution of conductances.Thermodynamics with multiple conserved quantities offers a promising direction for designing novel devices. For example, Vaccaro and Barnett's [J. A. Vaccaro and S. M. Barnett, Proc. R. Soc. A 467, 1770 (2011)1364-502110.1098/rspa.2010.0577; S. M. Barnett and J. A. Vaccaro, Entropy 15, 4956 (2013)ENTRFG1099-430010.3390/e15114956] proposed information erasure scheme, where the cost of erasure is solely in terms of a conserved quantity other than energy, allows for new kinds of heat engines. In recent work, we studied the discrete fluctuations and average bounds of the erasure cost in spin angular momentum. Here we clarify the costs in terms of the spin equivalent of work, called spinlabor, and the spin equivalent of heat, called spintherm. We show that the previously found bound on the erasure cost of γ^-1ln2 can be violated by the spinlabor cost, and only applies to the spintherm cost. We obtain three bounds for spinlabor for different erasure protocols and determine the one that provides the tightest bound. For completeness, we derive a generalized Jarzynski equality and probability of violation which shows that for particular protocols the probability of violation can be surprisingly large. We also derive an integral fluctuation theorem and use it to analyze the cost of information erasure using a spin reservoir.Jamming and percolation transitions in the standard random sequential adsorption of particles on regular lattices are characterized by a universal set of critical exponents. The universality class is preserved even in the presence of randomly distributed defective sites that are forbidden for particle deposition. However, using large-scale Monte Carlo simulations by depositing dimers on the square lattice and employing finite-size scaling, we provide evidence that the system does not exhibit such well-known universal features when the defects have spatial long-range (power-law) correlations. The critical exponents ν_j and ν associated with the jamming and percolation transitions, respectively, are found to be nonuniversal for strong spatial correlations and approach systematically their own universal values as the correlation strength is decreased. More crucially, we have found a difference in the values of the percolation correlation length exponent ν for a small but finite density of defects with strong spatial correlations. Furthermore, for a fixed defect density, it is found that the percolation threshold of the system, at which the largest cluster of absorbed dimers first establishes the global connectivity, gets reduced with increasing the strength of the spatial correlation.We consider the evolution of arbitrarily large perturbations of a prescribed pure hydrodynamical flow of an electrically conducting fluid. We study whether the flow perturbations as well as the generated magnetic fields decay or grow with time and constitute a dynamo process. For that purpose we derive a generalized Reynolds-Orr equation for the sum of the kinetic energy of the hydrodynamic perturbation and the magnetic energy. The flow is confined in a finite volume so the normal component of the velocity at the boundary is zero. The tangential component is left arbitrary in contrast with previous works. https://www.selleckchem.com/products/Teniposide(Vumon).html For the magnetic field we mostly employ the classical boundary conditions where the field extends in the whole space. We establish critical values of hydrodynamic and magnetic Reynolds numbers below which arbitrarily large initial perturbations of the hydrodynamic flow decay. This involves generalization of the Rayleigh-Faber-Krahn inequality for the smallest eigenvalue of an elliptic operator. For high Reynolds number turbulence we provide an estimate of critical magnetic Reynolds number below which arbitrarily large fluctuations of the magnetic field decay.
Motivated by developing a simple, accurate, and widely applicable approach to incorporate the finite barrier correction in analytical calculation of the escape rate, the reactive flux theory for finite barriers is proposed. For higher temperatures, instead of at the top of the barrier in the original reactive flux theory, the starting point of the trajectories of Brownian particles is removed into a position inside the potential well where the probability distribution can be regarded as an equilibrium one, and the potential barrier is replaced with an equivalent parabolic potential barrier. The equivalent potential barrier frequency can be obtained by two schemes. The population is also calculated more realistically for finite barriers. The theoretical method is tested by a Brownian particle moving in a cubic metastable potential and subjected to Gaussian white noise. The numerical simulation results confirm the approach satisfactorily until lower reduced barrier heights.Statistical mechanics is an important tool for understanding polymer electroelasticity because the elasticity of polymers is primarily due to entropy. However, a common approach for the statistical mechanics of polymer chains, the Gaussian chain approximation, misses key physics. By considering the nonlinearities of the problem, we show a strong coupling between the deformation of a polymer chain and its dielectric response, that is, its net dipole. When chains with this coupling are cross linked in an elastomer network and an electric field is applied, the field breaks the symmetry of the elastomer's elastic properties and, combined with electrostatic torque and incompressibility, leads to intrinsic electrostriction. Conversely, deformation can break the symmetry of the dielectric response, leading to volumetric torque and asymmetric actuation. Both phenomena have important implications for designing high-efficiency soft actuators and soft electroactive materials, and the presence of mechanisms for volumetric torque, in particular, can be used to develop higher degree of freedom actuators and to achieve bioinspired locomotion.We consider several limiting cases of the joint probability distribution for a random matrix ensemble with an additional interaction term controlled by an exponent γ (called the γ ensembles). The effective potential, which is essentially the single-particle confining potential for an equivalent ensemble with γ=1 (called the Muttalib-Borodin ensemble), is a crucial quantity defined in solution to the Riemann-Hilbert problem associated with the γ ensembles. It enables us to numerically compute the eigenvalue density of γ ensembles for all γ>0. We show that one important effect of the two-particle interaction parameter γ is to generate or enhance the nonmonotonicity in the effective single-particle potential. For suitable choices of the initial single-particle potentials, reducing γ can lead to a large nonmonotonicity in the effective potential, which in turn leads to significant changes in the density of eigenvalues. For a disordered conductor, this corresponds to a systematic decrease in the conductance with increasing disorder. This suggests that appropriate models of γ ensembles can be used as a possible framework to study the effects of disorder on the distribution of conductances.Thermodynamics with multiple conserved quantities offers a promising direction for designing novel devices. For example, Vaccaro and Barnett's [J. A. Vaccaro and S. M. Barnett, Proc. R. Soc. A 467, 1770 (2011)1364-502110.1098/rspa.2010.0577; S. M. Barnett and J. A. Vaccaro, Entropy 15, 4956 (2013)ENTRFG1099-430010.3390/e15114956] proposed information erasure scheme, where the cost of erasure is solely in terms of a conserved quantity other than energy, allows for new kinds of heat engines. In recent work, we studied the discrete fluctuations and average bounds of the erasure cost in spin angular momentum. Here we clarify the costs in terms of the spin equivalent of work, called spinlabor, and the spin equivalent of heat, called spintherm. We show that the previously found bound on the erasure cost of γ^-1ln2 can be violated by the spinlabor cost, and only applies to the spintherm cost. We obtain three bounds for spinlabor for different erasure protocols and determine the one that provides the tightest bound. For completeness, we derive a generalized Jarzynski equality and probability of violation which shows that for particular protocols the probability of violation can be surprisingly large. We also derive an integral fluctuation theorem and use it to analyze the cost of information erasure using a spin reservoir.Jamming and percolation transitions in the standard random sequential adsorption of particles on regular lattices are characterized by a universal set of critical exponents. The universality class is preserved even in the presence of randomly distributed defective sites that are forbidden for particle deposition. However, using large-scale Monte Carlo simulations by depositing dimers on the square lattice and employing finite-size scaling, we provide evidence that the system does not exhibit such well-known universal features when the defects have spatial long-range (power-law) correlations. The critical exponents ν_j and ν associated with the jamming and percolation transitions, respectively, are found to be nonuniversal for strong spatial correlations and approach systematically their own universal values as the correlation strength is decreased. More crucially, we have found a difference in the values of the percolation correlation length exponent ν for a small but finite density of defects with strong spatial correlations. Furthermore, for a fixed defect density, it is found that the percolation threshold of the system, at which the largest cluster of absorbed dimers first establishes the global connectivity, gets reduced with increasing the strength of the spatial correlation.We consider the evolution of arbitrarily large perturbations of a prescribed pure hydrodynamical flow of an electrically conducting fluid. We study whether the flow perturbations as well as the generated magnetic fields decay or grow with time and constitute a dynamo process. For that purpose we derive a generalized Reynolds-Orr equation for the sum of the kinetic energy of the hydrodynamic perturbation and the magnetic energy. The flow is confined in a finite volume so the normal component of the velocity at the boundary is zero. The tangential component is left arbitrary in contrast with previous works. https://www.selleckchem.com/products/Teniposide(Vumon).html For the magnetic field we mostly employ the classical boundary conditions where the field extends in the whole space. We establish critical values of hydrodynamic and magnetic Reynolds numbers below which arbitrarily large initial perturbations of the hydrodynamic flow decay. This involves generalization of the Rayleigh-Faber-Krahn inequality for the smallest eigenvalue of an elliptic operator. For high Reynolds number turbulence we provide an estimate of critical magnetic Reynolds number below which arbitrarily large fluctuations of the magnetic field decay.
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