We imaged the pore-scale distribution of air and water within packed columns of glass spheres of different textures using x-ray microcomputed tomography after primary drainage and after secondary imbibition. https://www.selleckchem.com/products/Tranilast.html Postimbibition residual air saturation increases with roughness size. Clusters larger than a critical size of about 15 to 40 pores are distributed according to a power law, with exponents ranging from τ=2.29±0.04 to 3.00±0.13 and displaying a weak negative correlation with roughness size. The largest cluster constitutes 7 to 20% of the total residual gas saturation, with no clear correlation with roughness size. These results imply that activities that enhance grain roughness by, e.g., creating acidic conditions in the subsurface, will promote capillary trapping of nonwetting phases under capillary-dominated conditions. Enhanced trapping, in turn, may be desirable in some engineering applications such as geological CO_2 storage, but detrimental to others such as groundwater remediation and hydrocarbon recovery.Numerical solutions of the mode-coupling theory (MCT) equations for a hard-sphere fluid confined between two parallel hard walls are elaborated. The governing equations feature multiple parallel relaxation channels which significantly complicate their numerical integration. We investigate the intermediate scattering functions and the susceptibility spectra close to structural arrest and compare to an asymptotic analysis of the MCT equations. We corroborate that the data converge in the β-scaling regime to two asymptotic power laws, viz. the critical decay and the von Schweidler law. The numerical results reveal a nonmonotonic dependence of the power-law exponents on the slab width and a nontrivial kink in the low-frequency susceptibility spectra. We also find qualitative agreement of these theoretical results to event-driven molecular dynamics simulations of polydisperse hard-sphere systems. In particular, the nontrivial dependence of the dynamical properties on the slab width is well reproduced.While cracks in isotropic homogeneous materials propagate straight, perpendicularly to the tensile axis, cracks in natural and synthetic composites deflect from a straight path, often increasing the toughness of the material. Here we combine experiments and simulations to identify materials properties that predict whether cracks propagate straight or kink on a macroscale larger than the composite microstructure. Those properties include the anisotropy of the fracture energy, which we vary several fold by increasing the volume fraction of orientationally ordered alumina (Al_2O_3) platelets inside a polymer matrix, and a microstructure-dependent process zone size that is found to modulate the additional stabilizing or destabilizing effect of the nonsingular stress acting parallel to the crack. Those properties predict the existence of an anisotropy threshold for crack kinking and explain the surprisingly strong dependence of this threshold on sample geometry and load distribution.We address the out-of-equilibrium dynamics of a many-body system when one of its Hamiltonian parameters is driven across a first-order quantum transition (FOQT). In particular, we consider systems subject to boundary conditions favoring one of the two phases separated by the FOQT. These issues are investigated within the paradigmatic one-dimensional quantum Ising model, at the FOQTs driven by the longitudinal magnetic field h, with boundary conditions that favor the same magnetized phase (EFBC) or opposite magnetized phases (OFBC). We study the dynamic behavior for an instantaneous quench and for a protocol in which h is slowly varied across the FOQT. We develop a dynamic finite-size scaling theory for both EFBC and OFBC, which displays some remarkable differences with respect to the case of neutral boundary conditions. The corresponding relevant timescale shows a qualitative different size dependence in the two cases it increases exponentially with the size in the case of EFBC, and as a power of the size in the case of OFBC.We present an alternative type of parity-time (PT)-symmetric generalized Scarf-II potentials, which makes possible for non-Hermitian Hamiltonians in the classical linear Schrödinger system to possess fully real spectra with unique features such as the multiple PT-symmetric breaking behaviors and to support one-dimensional (1D) stable PT-symmetric solitons of power-law waveform, namely power-law solitons, in focusing Kerr-type nonlinear media. Moreover, PT-symmetric high-order solitons are also derived numerically in 1D and 2D settings. Around the exactly obtained nonlinear propagation constants, families of 1D and 2D localized nonlinear modes are also found numerically. The majority of fundamental nonlinear modes can still keep steady in general, whereas the 1D multipeak solitons and 2D vortex solitons are usually susceptible to suffering from instability. Likewise, similar results occur in the defocusing Kerr-nonlinear media. The obtained results will be useful for understanding the complex dynamics of nonlinear waves that form in PT-symmetric nonlinear media in other physical contexts.It is well known that Brownian ratchets can exhibit current reversals, wherein the sign of the current switches as a function of the driving frequency. We introduce a spatial discretization of such a two-dimensional Brownian ratchet to enable spectral methods that efficiently compute those currents. These discrete-space models provide a convenient way to study the Markovian dynamics conditioned upon generating particular values of the currents. By studying such conditioned processes, we demonstrate that low-frequency negative values of current arise from typical events and high-frequency positive values of current arises from rare events. We demonstrate how these observations can inform the sculpting of time-dependent potential landscapes with a specific frequency response.We consider a quantum system such as a qubit, interacting with a bath of fermions as in the Fröhlich polaron model. The interaction Hamiltonian is thus linear in the system variable and quadratic in the fermions. Using the recently developed extension of Feynman-Vernon theory to nonharmonic baths we evaluate quadratic and the quartic terms in the influence action. We find that for this model the quartic term vanish by symmetry arguments. Although the influence of the bath on the system is of the same form as from bosonic harmonic oscillators up to effects to sixth order in the system-bath interaction, the temperature dependence is nevertheless rather different, unless rather contrived models are considered.