Arsenite (As(III)) is more toxic and difficult to remove than arsenate (As(V)). In this study, an S-doped Cu-La bimetallic oxide (S-CuLaO) decorated with metal-organic framework (MOF) composite (S-CuLaO@UIO-66) was synthesized and applied for the adsorption of As(III). The maximum adsorption capacity of As(III) by S-CuLaO@UIO-66 was as high as 171 mg/g, which was much higher compared with other MOF compounds reported to date. The UIO-66 support improved the dispersion and reduced the size of the S-CuLaO particles, which increased the number of exposed adsorption reactive sites. Study of the mechanism revealed that the synchronous oxidation and adsorption significantly increased the removal of As(III). O2∙- was produced by the receiving electron from the dissolved oxygen from Cu(I) in S-CuLaO, which converted As(III) to As(V). Furthermore, the stability and reusability S-CuLaO@UIO-66 (without regeneration) was investigated at a low As(III) concentration (approximately 1000 µg/L) in deionized water and well water. The residual arsenic concentration ranged from 0.8 to 2.8 μg/L in deionized water and 3-58.2 μg/L in well water within 240 min during three cycles. Generally, this study suggests that combining an optimal oxide with a stable MOF is a promising approach for the fabrication of composite adsorbents.The dietary lead (Pb) risk across China was assessed based on the margin of exposure (MOE) approach by comparing the level (1.5 μg/kg/d) based on the Pb concentrations in foodstuffs from1386 published articles. The Pb averages of the 18 foods were lower than their corresponding limits enacted by the Chinese government, ranging from 0.09 to 0.30 mg/kg. Food from plants had a much higher contribution to dietary Pb intake than that from animals (86% vs. 14%), and cereals and vegetables contributed 79% of the Pb intake from plant-based food. Although each category of food contained a relatively low Pb concentration, the accumulated Pb from the total diet posed a high risk to human health. The MOE risk from dietary Pb averaged 1.57 and ranged from 0.13 to 6.18, with high risks in southern, southwestern, eastern, central, and northern China. The MOE risk from Pb could be decreased by adjusting the dietary structure, and the ratio of people categorized as high risk (MOE less then 1) would decrease from 56% to 37%, 41%, or 24% if the category of cereal or vegetable or both cereals and vegetables with the lowest Pb concentration in their local areas were selected, respectively.The metal-free graphitic carbon nitride is a promising photocatalyst for peroxymonosulfate (PMS) activation towards water decontamination, but bearing low efficiency due to its electronic structure and surface chemistry. Herein, the non-metallic element boron was adopted for catalyst development. The boron dopants and defects were simultaneously introduced by potassium borohydride, resulting in an excellent activity towards PMS activation. The dominant reactive oxygen species was singlet oxygen, which was determined to originate from PMS activation over photo-induced holes initiated by an electron transfer process. Calculations based on density functional theory revealed that at excited states, due to the dopants and defects, the electron-hole distribution was altered from an even population to a significant separation, which was beneficial for photocatalytic performance. Besides, the engineered electronic structure weakened the catalyst resistance to charge transfer, enabling easier electron transfer between the catalyst and the PMS. Moreover, the strengthened and enlarged positive electrostatic potential areas on heptazine rings oriented the electron transfer process from the negatively charged PMS to the catalyst, facilitating the generation of singlet oxygen. These findings provide underlying mechanism insights into the contribution of dopants and defects to catalytic performance on persulfate-based photocatalytic water treatment.Marine phycotoxins severely threaten ecosystem health and mariculture. This study investigates the spatial distribution and source of diverse phycotoxins in the South China Sea (SCS), during four 2019/2020 cruises. Saxitoxin (STX) and okadaic acid (OA) -groups, azaspiracids, cyclic imines, pectenotoxins (PTX), yessotoxins, and domoic acid (DA) toxins were analyzed in microalgal samples. PTX2 occurred with the highest (93.5%) detection rate (DR) during all cruises, especially in the Pearl River Estuary (PRE) in June 2019. https://www.selleckchem.com/products/oxythiamine-chloride-hydrochloride.html Homo-yessotoxin (hYTX) and DA were found during three cruises in August 2020, and high DR of hYTX (67.7%, 29.3%) and DA (29.0%, 29.3%) in the PRE and Guangdong coast, respectively, in June 2019 and 2020, peaking at concentrations of 777 pg hYTX L-1 and 38514 pg DA L-1. The phycotoxin distribution demonstrated that DA-producing microalgae gathered close to the PRE and Guangdong coast, while hYTX-producing microalgae distributed relatively far offshore. Microalgae producing PTX2- and STX-group toxins were more widely living in the SCS. High-throughput sequencing results suggested that Alexandrium pacificum and Gonyaulax spinifera were responsible for STX-group toxins and hYTX, respectively, while Pseudo-nitzschia cuspidata was the main source of DA. Widely distributed PTX2, hYTX, and DA were reported for the first time in the SCS.Heavy metal toxicity has become a pressing ecological problem that affects the ecosystems through bioaccumulation, representing a serious public health hazard. Many conventional strategies have been developed and applied to decontaminate and restore metal-contaminated areas. However, these conventional approaches are not very suitable and environmentally safe for heavy metal remediation because of their high operational costs, high energy requirements, post-waste disposal problems, and secondary pollutant generation. Thus, biosurfactant-based bioremediation of heavy metals is a sustainable and promising approach because of its biodegradation capability, economic effectiveness, and ecofriendly nature. Pseudomonas sp., Bacillus sp., Citrobacter freundii, and Candida tropicalis have been isolated as potential sources of biosurfactants and produce compounds such as surfactin, rhamnolipids, and sophorolipids. Owing to the severity of heavy metal pollution in certain parts of the environment, biosurfactants have garnered great interest and attention as an emerging multi-functional technology of the new century for successful removal of heavy metal pollutants.